2,6-pyridinedicarboxylic acid as an efficient and mild organocatalyst for the one-pot synthesis of xanthene derivative
محل انتشار: نشریه آسیایی شیمی سبز، دوره: 1، شماره: 1
سال انتشار: 1396
نوع سند: مقاله ژورنالی
زبان: انگلیسی
مشاهده: 547
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شناسه ملی سند علمی:
JR_AJGC-1-1_003
تاریخ نمایه سازی: 22 اردیبهشت 1397
چکیده مقاله:
Simple and efficient protocols have been developed for the one-pot synthesis of aryl-14H-dibenzo[a,j]xanthenes and 1,8-dioxo-octahydro- xanthenes. (i) A cost-effective, simple and convenient procedure for the synthesis of aryl-14H-dibenzo[a,j]xanthenes has been developed via a one-pot condensation from substituted benzaldehydes (1 equiv) and β- naphthol (2 equiv) in the presence of 2,6-pyridinedicarboxylic acid (2,6- PDCA) under solvent-free conditions. (ii) The one-pot condensation of substituted benzaldehydes (1 equiv) and 5,5-dimethyl-1,3- cyclohexanedione (dimedone) (2 equiv) in the presence of 2,6- pyridinedicarboxylic acid (2,6-PDCA) under solvent-free conditions leads to 1,8-dioxo-octahydro-xanthenes. In these protocols several advantages such as: excellent yields, very short reaction times, easy work-up, simple methodology are offered.
کلیدواژه ها:
نویسندگان
Sobhan Rezayati
Department of Chemistry, Payame Noor University,Tehran, Iran
Ehsan Mirzajanzadeh
Department of Chemistry, Qaemshahr Branch, Islamic Azad University, Qaemshahr, Iran
Hamed Seifournia
Department of Chemistry, Qaemshahr Branch, Islamic Azad University, Qaemshahr, Iran